イオン注入に立脚した難加工性材料の超精密剥離技術の開発

ឡ⥲◊࣭◊✲ሗ࿌
愛総研・研究報告
➨ 16 号 2014
ྕ 2014 年
ᖺ
第
19
࢖࢜ࣥὀධ࡟❧⬮ࡋࡓ㞴ຍᕤᛶᮦᩱࡢ㉸⢭ᐦ๤㞳ᢏ⾡ࡢ㛤Ⓨ
Development of Ultra-Precision Exfoliation Technology for
Hard-to-Process Materials
ᒾ⏣ ༤அ͊
Hiroyuki Iwata͊
Abstract
Hydrogen ion-implantation into Hard-to-Process Materials and subsequent heat treatment causes
dome-shaped gas-filled blisters and craters appear on the surface. This method becomes an attractive nano
fabrication technology having high accuracy and high environment-friendly process. We newly tried for this
technique to metal materials, such as titanium and aluminum-ally, and a CFRP composit material. When the
same conditions as a semiconductor crystal were used, in the aluminum Magnesium alloy, the separation
phenomenon was able to be found out on the surface. The existence of the crystalline phase considered to have
formed by the rolling has leaded exfoliation.
1䠊 ⥴ゝ
ᮏᏛࡀᡤᅾࡍࡿᆅᇦࡣࠊࡶࡢ࡙ࡃࡾ⏘ᴗࠊ≉࡟⮬ື㌴ࠊ
⾡ࡢ᭱㐺໬ࢆ㏣✲ࡍࡿࡇ࡜ࡶ㔜せ࡛࠶ࡿࠋࡲࡓࠊᅛయ⾲㠃
⯟✵ᶵࠊᕤసᶵᲔࡢୡ⏺ⓗ࡞⏘ᴗ㞟✚ᆅ࡛࠶ࡿ㸬 ᖺ
ࡢࢼࣀ࣭࣐࢖ࢡࣟᵓ㐀ࡣ⏺㠃⌧㇟࡟኱ࡁ࡞ᙳ㡪ࢆ୚࠼ࡿࡇ
࡟ྡྂᒇ࡛ &23㸦⏕≀ከᵝᛶ᮲⣙➨ ᅇ⥾⣙ᅜ఍㆟㸧
࡜ࡀ▱ࡽࢀ࡚࠸ࡿࡀࠊ⏕⏘ຍᕤࡢศ㔝࡛ࡢ฼⏝ࡣ⥴࡟ᑵ࠸
ࡀ㛤ദࡉࢀࠊࡑࡢ୰࡛⎔ቃ㈇Ⲵ㍍ῶࠊ&2 ๐ῶࡢ୰࡛〇ရ
ࡓࡤ࠿ࡾ࡛࠶ࡿࠋᚑ᮶࡟࡞࠸⢭ᗘࡢຍᕤᡭἲ࡞ࡽࡧ࡟ᕤල
ࡢ㍍㔞໬ࠊ㧗ᛶ⬟໬ࡀᙉࡃồࡵࡽࢀࡓࠋ
ᨵⰋ࠾ࡼࡧ⿕ຍᕤᮦᩱ࡟ᅛయᵓ㐀๰〇ᶵ⬟ࢆ୚࠼ࡿࡇ࡜
⮬ື㌴⏘ᴗ࡛ࡣࠊ ᖺᗘ᪂⇞㈝ᇶ‽࡬ࡢᑐᛂࡀ኱ࡁ
࡛ࠊ㣕㌍ⓗ࡞⏕⏘⬟⋡ࠊ〇ရ⢭ᗘࡀᚓࡽࢀࡿࠋࢼࣀ࣭࣐࢖
࡞ㄢ㢟࡜࡞ࡗ࡚࠾ࡾࠊ㌴య㔜㔞ࡢ㍍㔞໬ࢆᙉຊ࡟᥎㐍ࡍࡿ
ࢡࣟຍᕤ࡟࠾࠸࡚ࡣ༢⤖ᬗࢆࡣࡌࡵ࡜ࡍࡿ㞴ຍᕤᛶᕤල
ᚲせࡀ࠶ࡾࠊ㧗ᙉᗘ㗰࡟ᑐࡍࡿప㈇Ⲵ⎔ቃᛶࡢຍᕤᢏ⾡ࠊ
࡬ࡢ࢖࢜ࣥὀධ࡞࡝᪂つࡢᢏ⾡ᑟධࡀᚲせ࡛࠶ࡿࠋ
㕲㗰ᮦᩱ࢔࣑ࣝࢽ࣒࢘ࡲࡓࡣ࣐ࢢࢿࢩ࣒࢘ྜ㔠࡞࡝␗✀
࢖࢜ࣥὀධࡣ༙ᑟయ⏘ᴗࡢ୰࡛ࡣ㛗ࡃせ⣲ᢏ⾡࡜ࡋ࡚
ᮦᩱ㛫ࡢ᥋ྜᢏ⾡ࡢ㛤Ⓨࡀồࡵࡽࢀ࡚࠸ࡿࠋࡲࡓࠊ⯟✵ᶵ
⏝࠸ࡽࢀ࡚࠸ࡿࠋ┠ⓗࡣ㺂SQ༙ᑟయ㡿ᇦࡢᙧᡂࡢࡓࡵࡢࢻ
⏘ᴗ࡛ࡣࠊ&)53 ࡀ㍍㔞໬ࡢษࡾᮐ࡜ࡋ࡚౑ࢃࢀጞࡵࡓ
ࡀࠊ〇㐀㸦ᡂᙧ㸧ࠊຍᕤᕤ⛬࡟࠸ࡲࡔ኱ࡁ࡞ㄢ㢟ࢆṧࡋ࡚
࠸ࡿࠋࡲࡓ⪏⇕ྜ㔠ࡸࢳࢱࣥྜ㔠ࡶ⯟✵ᶵ㒊ရ࡜ࡋ࡚ከࡃ
౑ࢃࢀ࡚࠸ࡿࡀࠊࡑࡢຍᕤ࡟ࡣከࡃࡢ᫬㛫࡜࢚ࢿࣝࢠ࣮ࢆ
࣮ࣃࣥࢺὀධ㸪ࢹࣂ࢖ࢫࡢ㟁Ẽ≉ᛶࡢ㧗⢭ᗘ໬㸦ࣛ࢖ࣇࢱ
࢖࣒ไᚚ㸪ࢻࢼ࣮୙άᛶ໬㸪ὀධḞ㝗పῶ㸧࡞࡝ᵝࠎ࡛࠶
ࡿࠋᮦᩱຍᕤ࡬ࡢᛂ⏝ࡢⓎ➃ࡣ㸪ཎᏊ⅔ࡢෆቨࡢᨺᑕ⥺࡟
㈝ࡸࡉࢀ࡚࠸ࡿࡢࡀ⌧≧࡛࠶ࡿࠋࡇࢀࡽࡢᮦᩱࡢຍᕤ⬟
ࡼࡿ⬤໬࡜⪃࠼ࡽࢀࡿࠋ㏆ᖺ࡛ࡣ࢖࣑࢜ࣥࣜࣥࢢ⿦⨨ࡸ㞟
⋡ࠊప⎔ቃ㈇Ⲵᛶࡢ㣕㌍ⓗ࡞ྥୖࡀᙉࡃồࡵࡽࢀ࡚࠸ࡿࠋ
᮰࢖࢜ࣥࣅ࣮࣒ຍᕤ⿦⨨࡞࡝ࢹࣂ࢖ࢫຍᕤࡢ㡿ᇦ࡛ࡶᚲ
୍᪉ࠊ〇ရ࡜ࡋ࡚ࡢᛶ⬟ࢆྥୖࡉࡏࡿࡓࡵ࡟ࠊሬ⿦࣭⁐ᑕ࣭
㡲ࡢᢏ⾡࡜ࡋ࡚⏝㏵ࡣᣑ኱ࡋ࡚࠸ࡿࠋࡲࡓ㧗࢚ࢿࣝࢠ࣮࢖
ࢥ࣮ࣝࢻࢫࣉ࣮ࣞ➼ࢆྵࡵࡓྛ✀⾲㠃ฎ⌮ࠊ࣐࢖ࢡࣟ㺃ࢼ
࢜ࣥࡢᛂ⏝౛࡜ࡋ࡚ࣛࢨࣇ࢛࣮ࢻᚋ᪉ᩓ஘㸦5%6㸧㸪ᙎᛶ
ࣀᵓ㐀ࡢ௜୚ࡶ㔜せ࡞ㄢ㢟࡛࠶ࡿ㸬ࡉࡽ࡟ྛ✀せ⣲ᢏ⾡㛫
ࡢᚭᗏࡋࡓ㐃ᦠ࣭㐃㙐࡟ࡼࡾࠊᕷሙࢽ࣮ࢬ࡟ᛂ࠼ࡿୖ࡛ᢏ
͊ ឡ▱ᕤᴗ኱Ꮫ ᕤᏛ㒊㟁ẼᏛ⛉㸦㇏⏣ᕷ㸧
ឡ▱ᕤᴗ኱Ꮫ ⥲ྜᢏ⾡◊✲ᡤ㸦㇏⏣ᕷ㸧
཯㊴⢏Ꮚ᳨ฟἲ㸦(5'$㸧ࢆࡣࡌࡵ࡜ࡍࡿࢹࣂ࢖ࢫࡢᵓ㐀ホ
౯࣭ศᯒホ౯ࡀᣲࡆࡽࢀࡿ㸬
ឡ▱ᕤᴗ኱Ꮫ⥲ྜᢏ⾡◊✲ᡤ◊✲ሗ࿌㸪➨ 16
愛知工業大学総合技術研究所研究報告,第
16 ྕ㸪2014
号,2014ᖺ
年
20
(a)
10ʅm
(b)
10ʅm
Figure 1 Cross-section TEM image of Si
Figure 3 Heated surface of
and Al-Mg Alloy(b)
Si(a)
Figure 2 Cross-section TEM image of Al-Mg
Alloy
ᖺ࡟%OXHOࡽࡣ62,༙ᑟయ࢙࢘ࣁࡢస〇ࣉࣟࢭࢫ
࡟࠾࠸࡚㸪ⷧ⭷άᛶᒙࡢ๤㞳ཬࡧ㌿㏦ᢏ⾡࡟Ỉ⣲࢖࢜ࣥὀ
㸬ᐇ㦂᪉ἲ
ධࢆ⏝࠸ࡓ㹙㸯㹛ࡇ࡜ࡣ༙ᑟయࣉࣟࢭࢫ࡬ࡢᛂ⏝࡟࠾࠸࡚㔜
せ࡞ᒎ㛤Ⅼ࡜࡞ࡗࡓ㸬ࢩࣜࢥࣥᨭᣢᇶᯈ࡜ぶỈᛶ㈞ࡾྜࢃ
ḟୡ௦ࡢ㍺㏦⏝ᶵჾ࡟⏝࠸ࡿࡇ࡜ࡀ᭷ຊどࡉࢀ࡚࠸ࡿ
ࡏࡉࢀࡓ㓟໬⭷௜࢖࢜ࣥὀධᇶᯈ࠿ࡽຍ⇕ฎ⌮࡟ࡼࡾ▐
㍍㔞࠿ࡘ㧗๛ᛶ࡞⣲ᮦࢆࢱ࣮ࢤࢵࢺ࡜ࡋࡓࠋ㔠ᒓᮦᩱ࡜ࡋ
᫬࡟ⷧ⭷ᒙࡀྲྀࡾฟࡉࢀࡿࡶࡢ࡛࠶ࡾࠊ㧗࠸⤖ᬗᛶࠊ㧗⢭
࡚ࡣ࢔࣑ࣝྜ㔠㸦$O0J0J㸧ࠊ࣐ࢢࢿࢩ࣒࢘ྜ㔠㸦$=㸹
ᗘ࠿ࡘ┬㈨※㸦࢟ࣜࡋࢁࡣQP࣮࢜ࢲ㸧➼ࡢ≉ᚩࢆᣢࡘࠋ㧗
$O㸧ࠊࡑࡋ࡚ࢳࢱࣥࠋ」ྜᮦᩱ࡜ࡋ࡚ࡣࠊ&)53ࠊ࠾ࡼࡧ
㞟✚㸪㧗㏿࠿ࡘపᾘ㈝㟁ຊࢆᐇ⌧ࡍࡿ62,ᵓ㐀ࢹࣂ࢖ࢫࡢ
࣮࢝࣎ࣥࢢࣛࣇ࢓࢖ࢺᯈࢆྲྀࡾୖࡆࡓࠋࢩࣜࢥࣥ➼༙ᑟయ
స〇࡟᭱㐺࡞ࣉࣟࢭࢫ࡜࡞ࡗ࡚࠸ࡿࠋ
⤖ᬗᮦᩱ࡟࠾࠸࡚๤㞳ࡀ㉳ࡁࡿ᮲௳࡜ྠ➼ࡢ᮲௳㸦ὀධ࢚
ࡇࡢⷧ⭷ᙧᡂ࣓࢝ࢽࢬ࣒ࡢ㘽ࡣỈ⣲ࣈࣜࢫࢱࣜࣥࢢ⌧
㇟࡟࠶ࡾ㸪࢖࢜ࣥὀධࡉࢀࡓỈ⣲ࡀຍ⇕࡟ࡼࡾ෇┙≧✵Ὕ
ࢿࣝࢠ࣮㸸NH9㸪ࢻ࣮ࢬ㔞㸸[FP㸫㸰㸧࡟࡚Ỉ⣲࢖
࢜ࣥὀධࢆ⾜ࡗࡓࠋ
ࢆᙧᡂࡋࠊ⾲㠃࠿ࡽ୍ᐃࡢ῝ࡉࡢ㊥㞳࡛ࡑࢀࡽࡀ㐃⤖ࡋୖ
ຍ⇕୰ࡢ⤒㐣ࢆほᐹࡍࡿࡓࡵຍ⇕ࢫࢸ࣮ࢪࢆ⿦ഛࡋࡓ
ᒙ㒊ࢆᘬࡁ๤ࡀࡍᡭἲ࡛࠶ࡿࠋࡶࡗࡥࡽ༙ᑟయ⤖ᬗ
ගᏛ㢧ᚤ㙾ࢆ⏝࠸㸪❅⣲㞺ᅖẼ୰ࡑࡢሙຍ⇕ほᐹࢆ⾜࡞ࡗ
6L6,&➼㸧ࡢຍᕤ࡟฼⏝ࡉࢀ>@ࠊ㔠ᒓ࣭」ྜᮦᩱ࡞࡝௚
ࡓ㸬300Υ࡞࠸ࡋࡣ700Υࡲ࡛ຍ⇕ࡋ㸪ヨᩱ⾲㠃࡟Ⓨ⏕ࡍࡿ
ࡢᮦᩱ࡬ࡢᛂ⏝౛ࡣ↓࠸ࠋࡇࡇ࡛ࡣࠊ㔠ᒓᮦᩱ࠾ࡼࡧ」ྜ
ࣈࣜࢫࢱࣜࣥࢢ(㝯㉳)ཬࡧ๤㞳ࢆほᐹࡋࡓ㸬ຍ⇕ᚋヨᩱࡢ
ᮦᩱ࡬ࡢᛂ⏝ࡢྍྰࢆ᫂ࡽ࠿࡟ࡍ࡭ࡃࠊᢏ⾡ᛂ⏝ࡢྍ⬟ᛶ
⾲㠃ࡣࠊSEM࠶ࡿ࠸ࡣSPMࢆ⏝࠸ヲ⣽࡞ᙧ≧ィ ࢆ⾜࡞ࡗ
ࡢ᳨ド࡜ࡑࡢᇶ♏㈨ᩱࢆᚓࡿࡇ࡜ࢆ┠ⓗ࡜ࡋࡓࠋ
ࡓ㸬ヨᩱෆ㒊ࡢᵓ㐀ࡣTEMࢆ⏝࠸ࡓ᩿㠃ほᐹ࠿ࡽホ౯ࡍ
ࡿ㸬
࢖࢜ࣥὀධ࡟❧⬮ࡋࡓ㞴ຍᕤᛶᮦᩱࡢ㉸⢭ᐦ๤㞳ᢏ⾡ࡢ㛤Ⓨ
イオン注入に立脚した難加工性材料の超精密剥離技術の開発
Figure 4 Cross sectional TEM image of ion implanted hard-to-process materials
Figure 5 SEM surface image of Mg-Al Alloy(AZ31) and Cross-sectinonal TEM image 㸬ᐇ㦂⤖ᯝ
㸦)LJE㸧ࠋࡇࢀࡽ๤㞳➼ࡢ⌧㇟ࡢ᭷↓ࡢ⌮⏤ࢆ᥈ࡿࡓ
ࡵࠊࡑࢀࡒࢀࡢᮦᩱࡢ࢖࢜ࣥὀධᚋ࠿ࡘຍ⇕๓ࡢヨᩱࡢ᩿
NH9 ࡢ࢚ࢿࣝࢠ࣮࡛Ỉ⣲࢖࢜ࣥࢆὀධࡉࢀࡓヨᩱ࡛
㠃ࢆ㏱㐣ᆺ㟁Ꮚ㢧ᚤ㙾࡟ࡼࡗ࡚ࡑࡢᵓ㐀ࢆホ౯ࡋࡓ
ࡣ⾲㠃࠿ࡽ ȣP ᙅࡢ῝ࡉ࡟࢖࢜ࣥὀධḞ㝗ᒙࢆᙧᡂࡍ
)LJࠋ๤㞳࠾ࡼࡧࣈࣜࢫࢱࣜࣥࢢࡀⓎ⏕ࡋࡓᮦᩱࡢඹ
ࡿ㸬࢖࢜ࣥὀධᚋࡢ 6L ࡢḞ㝗ᒙࡢᵝᏊࢆᅗ ࡟♧ࡍ㸬
$O0J
㏻ⅬࡣࠊỈ⣲⃰ᗘࡀࣆ࣮ࢡ࡜࡞ࡿ῝ࡉ࡛⣲ᮦࡢ༢⤖ᬗᵓ㐀
ྜ㔠ࡢ᩿㠃࡟ࡣ )LJ ࡀ♧ࡍࡼ࠺࡟Ḟ㝗ᒙࡀ⤖ᬗࡢ┦ᵓ㐀
ࡀᏑᅾࡋ࡚࠸ࡿࡇ࡜࡛࠶ࡗࡓࠋ$O0J ྜ㔠ࡣࠊᅽᘏ᫬࡟ᯒ
ࡢ୰࡟ほᐹࡉࢀࡿ㸬࢖࢜ࣥὀධᚋヨᩱࢆຍ⇕ࡋࡓ⤖ᯝࠊ࢔
ฟ࡟ࡼࡾ⾲㠃࡟ᖹ⾜࡞ከᒙࡢ⤖ᬗ┦ᵓ㐀ࡀᙧᡂࡉࢀ࡚࠾
࣑࣭࣐ࣝࢢࢿࢩ࣒࢘㸦$O0J0J㸧ࡢྜ㔠࡛ࡣࠊ)LJD
ࡾࠊࡇࢀࡽࡢᏑᅾࡀ࢞ࢫࢆྵࡴ✵ஈࡢ⭾ᙇ᫬࡟๤㞳➼ࡢ⌧
࡟♧ࡍࢩࣜࢥࣥ࡜ྠᵝ࡟⾲㠃࡟┤ᚄ ȣP ⛬ᗘࡢᒁᡤⓗ⭾
㇟ࢆᑟࡁࡸࡍࡃࡍࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋ
ࡽࡳ㸦ࣈࣜࢫࢱࣜࣥࢢ㸧ࡸ๤㞳ࡢⓎ⏕ࡀほᐹࡉࢀࡓ
21
ឡ▱ᕤᴗ኱Ꮫ⥲ྜᢏ⾡◊✲ᡤ◊✲ሗ࿌㸪➨ 16
愛知工業大学総合技術研究所研究報告,第
16 ྕ㸪2014
号,2014 ᖺ
年
22
Figure 6 Cross-sectional TEM image of Al-Mg Alloy(a) and CFRP(b)
୍᪉ 0J ྜ㔠㸦$=㸹$O)LJ㸧࡛ࡣࠊຍ⇕୰ࡢࣈࣜ
㏱㐣ᆺ㟁Ꮚ㢧ᚤ㙾ἲ࡟ࡼࡾホ౯ࡋࡓ࡜ࡇࢁࠊᅽᘏ᫬ࡢᯒฟ
ࢫࢱࣜࣥࢢࡣ୙᫂░࡛ࠊຍ⇕ᚋࡣ๤㞳࡜࿧ࡪࡼࡾ᪉ྥᛶࢆ
࡟ࡼࡾᙧᡂࡋࡓ࡜ᛮࢃࢀࡿ⤖ᬗ┦ࡢᏑᅾࡀࠊ๤㞳ࡢⓎ⏕ࢆ
ᣢࡘ͆࠼ࡄࢀ͇ᙧ≧ࡀᙧᡂࡉࢀࡓࠋࡼࡾၥ㢟࡞ࡢࡣࠊΥ
ᑟ࠸࡚࠸ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋࡇࡢࡇ࡜࠿ࡽࠊከ⤖ᬗࢆ୺య
ຍ⇕࡛⾲㠃࡟ࡣⓑⰍ໬ྜ≀ᒙ࡛そࢃࢀ࡚࠾ࡾࠊ┠ⓗ࡜ࡣ␗
࡜ࡍࡿ㔠ᒓᮦᩱ➼࡟࠾࠸࡚ࡶࠊ᮲௳࡟ࡼࡗ࡚Ỉ⣲࢖࢜ࣥὀ
࡞ࡿ⤖ᯝ࡜࡞ࡗࡓࡇ࡜࡛࠶ࡿࠋ࣐ࢢࢿࢩ࣒࢘ྜ㔠࡜ &)53
ධࢆ⏝࠸ࡓ๤㞳ᢏ⾡ࡀ㌿⏝ྍ⬟࡛࠶ࡿࡇ࡜ࢆ♧ࡍࡇ࡜ࡀ
ࡢ㏱㐣ᆺ㟁Ꮚ㢧ᚤ㙾࡟ࡼࡿᵓ㐀ゎᯒ࠿ࡽ㸪࢖࢜ࣥὀධᚋࡇ
࡛ࡁࡓࠋ
ࢀࡽࡢヨᩱࡢ᩿㠃ᵓ㐀࡟ࡣ㸪᫂☜࡞࢖࢜ࣥ↷ᑕ㡿ᇦࡀ⌧ࢀ
࡞࠸ࡇ࡜ࡀࢃ࠿ࡗࡓ㸬ࡇࢀࡽヨᩱ࡟࠾࠸࡚ࡣ㸪≀⌮ⓗ࡞స
ㅰ㎡
⏝ࡼࡾࡴࡋࢁ໬Ꮫⓗస⏝ࡀ⌧㇟ࡢせᅉ࡜࡞ࡗ࡚࠸ࡿࡇ࡜
ᮏ◊✲ࡢ୍㒊ࡣࠊᖹᡂ 22 ᖺᗘᩥ㒊⛉Ꮫ┬⚾❧኱Ꮫᡓ␎ⓗ◊
ࡀࢃ࠿ࡗࡓ㸬AlࠊTiࠊC-ࢢࣛࣇ࢓࢖ࢺࠊCFRP ࢆࡑࡢሙ
✲ᇶ┙ᙧᡂᨭ᥼⤒㈝㸦ࣉࣟࢪ࢙ࢡࢺ S1001033㸧࡞ࡽࡧ࡟බ
ຍ⇕ࢆ⾜ࡗࡓࡀࠊ⾲㠃ୖࡢኚ໬ࡣ࠶ࡿࡶࡢࡢࠊࣈࣜࢫࢱࣜ
┈㈈ᅋἲே⛉Ꮫᢏ⾡஺ὶ㈈ᅋ▱ࡢᣐⅬ࠶࠸ࡕ㔜Ⅼ◊✲ࣉࣟ
ࣥࢢ࠶ࡿ࠸ࡣ๤㞳⌧㇟ࡣ☜ㄆ࡛ࡁ࡞࠿ࡗࡓࠋAl-Mg ྜ㔠
ࢪ࢙ࢡࢺࡢ᥼ຓࢆཷࡅ࡚⾜ࢃࢀࡓࠋ࢖࢜ࣥὀධᐇ㦂ࡢ୍㒊
ࡢὀධ๓ࡢ᩿㠃 TEM ീ࠿ࡽࡣ⾲㠃࡟Ỉᖹ࡟ᒙᵓ㐀ࡀᙧᡂ
ࡣබ┈㈈ᅋἲேⱝ⊃‴࢚ࢿࣝࢠ࣮࡟࡚⾜ࢃࢀࡓ㸬ヨᩱస〇
ࡉࢀ࡚࠸ࡓ㸬」ྜᮦᩱ࡛࠶ࡿ CFRP ࡣࣞࢪࣥ(࢚࣏࢟ࢩᶞ
ࡢ୍㒊ࡣឡ▱⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࡟࡚ᐇ᪋ࡋࡓ㸬ࡲ
⬡)࡜Ⅳ⣲⧄⥔࡟ࡼࡿ」ྜᮦᩱ࡛࠶ࡿ㸬ෆ㒊࡟ྵࡲࢀࡿⅣ
ࡓࡈ༠ຊ㡬࠸ࡓᮏᏛᕤᏛ㒊㟁ẼᏛ⛉㟁Ꮚ᝟ሗᕤᏛᑓᨷᡤᒓ
⣲⧄⥔ࡣ┤ᚄ 5μm ࡛࠶ࡿ(ᅗ 6(b)ཧ↷)㸬ඖ᮶᭷ᶵ≀ࡢᶞ
ࡢᏛ⏕࡟⣬㠃ࢆ೉ࡾ࡚ឤㅰࡍࡿࠋᮏ◊✲ࡣࠊᖹᡂ 22 ᖺᗘᩥ
⬡࡛࠶ࡿࣞࢪࣥෆ࡟ὀධࡉࢀࡓ࢖࢜ࣥࡢ⑞㊧ࡣ☜ㄆ࡛ࡁ
㒊⛉Ꮫ┬⚾❧኱Ꮫᡓ␎ⓗ◊✲ᇶ┙ᙧᡂᨭ᥼⤒㈝㸦ࣉࣟࢪ࢙
ࡎ㸪ࡲࡓᩘ༑ nm ࡢ࣮࢜ࢲ࣮ࡢᨵ㉁ࢆ⾜࡞࠺࢖࢜ࣥὀධࡢ
ࢡࢺ S1001033㸧࡞ࡽࡧ࡟බ┈㈈ᅋἲே⛉Ꮫᢏ⾡஺ὶ㈈ᅋ▱
ຍᕤࡣᩘ࣑ࢡ࣮ࣟࣥ࢜ࢲࡢ⾲㠃⢒ᗘࡸෆ㒊ᵓ㐀ࢆᣢࡘ
ࡢᣐⅬ㔜Ⅼ◊✲ࣉࣟࢪ࢙ࢡࢺ㸦㞴ຍᕤᛶᮦᩱࡢ㉸⢭ᐦ࣭㧗
CFRP ࡟ࡣ⌧≧࡛ࡣ୙㐺࡛࠶ࡗࡓ㸬
⬟⋡ຍᕤᢏ⾡ࡢ㛤Ⓨ㸧ࡢ᥼ຓࢆཷࡅ࡚⾜ࢃࢀࡓࠋ୍㒊ࡢ࢖
࢜ࣥὀධࡣබ┈㈈ᅋἲேⱝ⊃‴࢚ࢿࣝࢠ࣮◊✲ࢭࣥࢱ࣮࡟
࡚ᐇ᪋ࡋࡓࠋヨᩱస〇࡞ࡽࡧ࡟ホ౯࡟ࡈ༠ຊ㡬࠸ࡓᮏᏛᏛ
4㸬 ⤖ゝ
Ỉ⣲࢖࢜ࣥὀධࢆ⏝࠸࡚༙ᑟయⷧ⭷ࢆᙧᡂࡍࡿᡭἲ
⏕ࠊ⏣ᐿὯ኱Ặ㸦⌧㸸ࢧ࢚࢝⌮◊ᕤᴗᰴᘧ఍♫㸧࡟⣬㠃ࢆ
೉ࡾ࡚ឤㅰࡍࡿࠋ
ࢆࠊ᪂ࡓ࡟ࢳࢱࣥࠊ࢔࣑ࣝ࡞࡝㔠ᒓᮦᩱࠊ&)53 ➼Ⅳ⣲⣔
」ྜᮦᩱ࡬㌿⏝ࢆヨࡳࡓࠋࢩࣜࢥࣥ➼ࡢ༙ᑟయ⤖ᬗ࡜ྠࡌ
ཧ⪃ᩥ⊩
᮲௳ࢆ⏝࠸ࡓ࡜ࡇࢁࠊ࢔࣑࣭࣐ࣝࢢࢿࢩ࣒࢘ྜ㔠࡟࠾࠸࡚
[1] M. Bruel, Electronics letters 31 (1995) 1201,
⾲㠃࡟๤㞳⌧㇟ࢆぢฟࡍࡇ࡜ࡀ࡛ࡁࡓࠋヨᩱࡢ᩿㠃ᵓ㐀ࢆ
[2] Q.Y. Tong, R.W. Bower, MRS Bulletin 23 (1998) 40